Enhanced electrosorption capacity of activated carbon electrodes for deionized water production through capacitive deionization
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Date
2020
Authors
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Publisher
Elsevier
Abstract
The deionized water (DI) of high purity standards is used in several industrial processes to manufacture products and technologies for high-end applications. Currently, DI water is produced by either reverse osmosis or continuous electrodeionization systems, however; both of them are facing several limitations. Therefore there is an urgent need for alternative technologies for DI water production. This study investigated the suitability of producing DI water by using capacitive deionization (CDI) with nitric acid-treated activated carbon electrodes (NTAC). Activated carbon (AC) was etched in nitric acid solution to introduce various oxygen functional groups on its surface. The Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy were used to confirm the increased surface oxygen-containing groups on AC after nitric acid treatment that enhanced its salt adsorption capacity. CDI experiments were conducted using a water solution of 12.0 μS/cm as a result DI water with the conductivity of 1.6 μS/cm (DI water grade III, according to International Organization of Standards) was produced. Also, electrochemical tests revealed good capacitive behaviour due to improved conductivity with NTAC having the highest specific capacitance of 381.7 F/g compared to 106.6 F/g of AC electrode. This study provides an insight into the electrosorption performance of materials in desalination of solutions of low ionic strength.
Description
Abstract. The full-text article is available at https://doi.org/10.1016/j.seppur.2020.116998
Keywords
Capacitive deionization, CDI, Deionized water, Activated carbon, Oxygen functional groups, Enhanced electrosorption, DI, DI water production, AC
Citation
Sufiani, O., Tanaka, H., Teshima, K., Machunda, R. L., & Jande, Y. A. (2020). Enhanced electrosorption capacity of activated carbon electrodes for deionized water production through capacitive deionization. Separation and Purification Technology, 116998.