Determination of surface charge density of α-alumina by acid - base titration

dc.contributor.authorNtalikwa, Justin W.
dc.date.accessioned2020-03-11T10:06:33Z
dc.date.available2020-03-11T10:06:33Z
dc.date.issued2007
dc.descriptionFull Text Article. Available at: http://www.ajol.info/index.php/bcse/article/download/61391/49544en_US
dc.description.abstractThe surface charge density (so) of colloidal alpha alumina suspended in various 1:1 electrolytes was measured using acid-base titration. An auto titrator capable of dispensing accurately 25 ± 0.1 μL of titrant was used. The pH and temperature in the titration cell were monitored using single junction electrodes and platinum resistance thermometers, respectively. A constant supply of nitrogen gas in the cell was used to maintain inert conditions. The whole set up was interfaced with a computer for easy data acquisition. It was observed that the material exhibits a point of zero charge (PZC), this occurred at pH of 7.8 ± 0.1, 7.6 ± 0.2, 8.5 ± 0.1, 8.3 ± 0.1 for NaCl, NaNO3, CsCl and CsNO3 systems, respectively. It was also observed that below PZC, so increases with increase in electrolyte concentration (Co) whereas above PZC, so decreases with increase in Co. It was concluded that so of this material is a function of pH and Co and that its polarity can be varied through zero by varying these parameters.en_US
dc.identifier.citationNtalikwa, J. W. (2007). Determination of surface charge density of α-alumina by acid-base titration. Bulletin of the Chemical Society of Ethiopia, 21(1).en_US
dc.identifier.urihttp://hdl.handle.net/20.500.12661/2139
dc.language.isoenen_US
dc.subjectAluminaen_US
dc.subjectSurface charge densityen_US
dc.subjectAcid-base titrationen_US
dc.subjectPZCen_US
dc.subjectPoint Zero Chargeen_US
dc.subjectTitrationen_US
dc.titleDetermination of surface charge density of α-alumina by acid - base titrationen_US
dc.typeArticleen_US
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